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| Round 4 Fixtures & Results |
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| Round 4 Leg 1 |
| 15-Feb-01 | AEK Athens | 0-1 | Barcelona | 24,000 | [details] | |
| | | Luis Enrique 41 |
| 15-Feb-01 | Alavés | 3-3 | Inter Milan | 16,000 | [details] | |
| Javi Moreno 43 | | A Recoba 45, 50 |
| O Tellez 70 | | C Vieri 65 |
| Ivan Alonso 73 | |
| 15-Feb-01 | AS Roma | 0-2 | Liverpool | 70,000 | [details] | |
| | | Owen 46, 72 |
| 15-Feb-01 | FC Porto | 3-1 | Nantes | 25,000 | [details] | |
| J Esquerdinha 17p | | H Ahamada 14 |
| N Gillet(og) 58 | |
| C Secretario 86 | |
| 15-Feb-01 | PSV Eindhoven | 2-1 | Parma | 30,000 | [details] | |
| A Ooijer 24 | | P Mboma 67 |
| D Rommedahl 73 | |
| 15-Feb-01 | Rayo Vallecano | 4-1 | Bordeaux | 7,500 | [details] | |
| R De Quintana 19 | | L Laslandes 2 |
| E Bolic 73 | |
| JM Quevedo 82 | |
| Michel 90 | |
| 15-Feb-01 | Stuttgart | 0-0 | Celta Vigo | 20,000 | [details] | |
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| 15-Feb-01 | Slavia Prague | 0-0 | Kaiserslautern | 17,840 | [details] | |
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| Round 4 Leg 2 |
| 22-Feb-01 | Barcelona | 5-0 | AEK Athens | 50,000 | [details] | |
| Luis Enrique 22, 31, 60 | (Agg: 6-0) |
| Rivaldo 57 | |
| Gerard 87p | |
| 22-Feb-01 | Bordeaux | 1-2 | Rayo Vallecano | 22,000 | [details] | |
| Mingo(og) 24 | (Agg: 2-6) | Luis Cembranos 20p |
| | | J Bolo 50 |
| 22-Feb-01 | Celta Vigo | 2-1 | Stuttgart | 20,000 | [details] | |
| V Karpin 6 | (Agg: 2-1) | S Blank 45 |
| A Mostovoi 85 | |
| 22-Feb-01 | Inter Milan | 0-2 | Alavés | 9,845 | [details] | |
| | (Agg: 3-5) | J Cruyff 78 |
| | | I Tomic 83 |
| 22-Feb-01 | Kaiserslautern | 1-0 | Slavia Prague | 28,000 | [details] | |
| V Lokvenc 59 | (Agg: 1-0) |
| 22-Feb-01 | Liverpool | 0-1 | AS Roma | 43,688 | [details] | |
| | (Agg: 2-1) | G Guigou 70 |
| 22-Feb-01 | Nantes | 2-1 | FC Porto | 29,000 | [details] | |
| M Vahirua 68 | (Agg: 3-4) | J Pena 35 |
| S Armand 74 | |
| 22-Feb-01 | Parma | 3-2 | PSV Eindhoven | 11,883 | [details] | |
| S Milosevic 64p, 69 | (Agg: 4-4) | D Rommedahl 32 |
| J Montano 90 | | M Kezman 45 |
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